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中国大学MOOC 慕课考研
SPOC学校专有课程
有机电子学(双语)
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spContent=有机电子学还处于发展和探索阶段,很多理论都借鉴于无机体系,没有形成定论。 本门课程从有机光电材料的性质与化学结构关系出发,对有机材料的光学和电学性质作了详细的论述;阐释了相关概念和机理,并介绍了重要的表征方法。相信该门课程对从事有机电子学研究的人员有很大的帮助。
—— 课程团队
课程概述

2000年,艾伦 黑格等人因为发现了导电聚合物被授予诺贝尔化学奖,开拓了有机电子学的新时代,在各种电子器件中,诸如场效应晶体管、太阳能电池、电致发光、存储、传感、激光器等,有机材料都相继出现并被证明有广阔的应用前景。因此,对材料、器件、物理等领域的全面理解和掌握,对有机电子学的发展十分必要。本门课程首先从有机光电材料的性质与化学结构关系出发,对有机材料的光学和电学性质作了详细的论述;阐释了相关概念和机理,并介绍了重要的表征方法;本门课程还介绍了有机光电材料的重要应用,如有机场效应晶体管、有机太阳能电池、有机电致发光等。在本课程中,我们将重点学习有机材料的基本概念和器件的工作机制。

成绩要求

通过本课程的学习,要求学生全面掌握以有机材料为基础的光电功能材料特性及其本质,同时对有机光电功能材料的器件应用。

本课程的成绩由课堂出勤率、小测验、翻转课堂表现期末(开卷)考试的成绩共同组成,分别占比5%、15%、30%和50%。总分满60分为合格,满90分为优秀。

课程大纲

Unit 1: Introduction to Organic Electronics

1.1 History and development of organic materials

1.2 Definition and classification/features of organic materials

1.3 Applications of organic materials in electronic devices

1.4 w1-中英文词汇表及音频

1.5 翻转课堂讨论题

Q1

Unit 2: Bonding and Corresponding Concepts/Properties in Solids

Q2

2.5 翻转课堂讨论题

2.1 Bonding types in solid, inter and intra molecular bonds in organic materials

2.2 Covalent Bond Theory

2.3 Types of covalent bonding and electrons in organic materials

2.4 w2-中英文词汇表及音频

Unit 3: Electronic Structure and Related Theories in Organic Materials

Q3

3.1 Molecular orbital theory and crystal/ligand field theories

3.2 Band theory

3.3 Electronic structure in organic materials

3.4 w3-中英文词汇表及音频

3.5 翻转课堂讨论题

Unit 4:  Molecular Interaction and Stacking

Q4

Quiz 4

4.1 Inter molecular forces

4.2 Crystal structures of organic materials

4.3 w4-中英文词汇表及音频

4.4 翻转课堂讨论题

Unit 5: Energy Related Processes in Organic Materials-I

Q5

5.1 Excited state related concepts

5.2 Absorption

5.3 Excited state decay processes in an isolated  organic molecule

5.4 w5-中英文词汇表及音频

5.5 翻转课堂讨论题

Unit 6: Energy Related Processes in Organic Materials-II

Q6

6.1 Nature of optical transition and Selection rules for optical transition

6.2 Franck-Condon principle and Einstein equation

6.3 Intensity distribution and fine structure in absorption spectrum and Emission quantum yield and excited state lifetime

6.4 w6-中英文词汇表及音频

6.5 翻转课堂讨论题

Unit 7: Energy Related Processes in Organic Materials-III __Excited states decay processes in organic aggregates

Q7

7.1 Davydov splitting

7.2 Excimer and exciplex

7.3 Fusion/annihilation and fission/splitting

7.4 w7-中英文词汇表及音频

7.5 翻转课堂讨论题

Unit 8: Energy Related Processes in Organic Materials-IV

Q8

8.1 Exciton generation and Exciton classification

8.2 Exciton transfer —— Energy migration/transfer

8.3 Exciton diffusion and Dynamic processes of exciton

8.4 w8-中英文词汇表及音频

8.5 翻转课堂讨论题

Unit 9: Electrical Properties and Related Processes in Organic Materials-I

Q9

9.1 Preliminary historical remarks

9.2 Basic concepts

9.3 Carrier types in organic materials

9.4 w9-中英文词汇表及音频

9.5 翻转课堂讨论题

Unit 10: Electrical Properties and Related Processes in Organic Materials-II

Q10

10.1 Intrinsic/doped carriers

10.2 Photogenerated carriers

10.3 Injected carriers

10.4 w10-中英文词汇表及音频

10.5  翻转课堂讨论题

Unit 11: Electrical Properties and Related Processes in Organic Materials-III

Q11

11.1 Three extreme modes for carrier transport

11.2 Carrier transport in organic crystal and disordered organic materials

11.3 Models for carrier transport in disordered organic materials

11.4 Conductive organic materials

11.5 w11-中英文词汇表及音频

11.6 翻转课堂讨论题

Unit 12:  Characterization of  Organic Materials

Q12

12.1 Thermal analysis, HOMO/LUMO and triplet state HOMO/LUMO

12.2 Carrier mobility, Work function and Photoluminescence quantum yield

12.3 w12-中英文词汇表及音频

12.4 翻转课堂讨论题

Unit 13: Organic Field Effect Transistors (OFETs)

Q13

13.1 Historical review/device structure/working principle of OFET

13.2 Performance characterization

13.3 Organic semiconductors for OFET

13.4 w13-中英文词汇表及音频

13.5 翻转课堂讨论题

Unit 14: Optoelectrical and Electrooptic Conversions in Organic devices

Q14

14.1 Organic materials included solar cells

14.2 Organic light-emitting diodes

14.3 w14-中英文词汇表及音频

14.4  翻转课堂讨论题

Unit 15: Organic Sensor, Memory and Laser

15.1 Organic Sensor

15.2 Organic Memory

15.3 Organic Laser

15.4 w15-中英文词汇表及音频

15.5 翻转课堂讨论题

预备知识

本课程需要部分《有机化学》和《半导体物理》的知识为基础。

参考资料

1. 教材

密保秀,高志强,曹大鹏《有机电子学双语教程》自编教材,2018 南京邮电大学

2. 主要参考书

黄维,密保秀,高志强.《有机电子学》科学出版社,2011元月出版

吴世康,汪鹏飞.有机电子学概论.化学工业出版社,2010

黄春辉,李富友,黄维著.有机电致发光材料与器件导论.复旦大学出版社,2005

Pope and Swenberg, Electronic Processes in Organic Crystals and Polymers, second edition, Oxford University Press1999

Forrest, “The path to ubiquitous and low-cost organic electronic applications on plastic,”Nature 428, 911, 2004

Nitzan and Ratner, “Review: Electron Transport in Molecular Wire Junctions,”Science 300, 1384, 2003